32005-36-0Bis(dibenzylideneacetone)palladium(0)Synonym: Palladium(0) bis(dibenzylideneacetone), Pd(dba)2CAS Number: 32005-36-0MDL: MFCD00051942Formula: C34H28O2PdFormula Weight: 575.00 g/molAppearance (Color) Brown to BlackCaution : air sensitiveshelf life :12 month ISO 9001 MAUNFACTURERpharmaceutical compounds OLED intermediates palladium catalystRelated Categories Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Development Quantities for Research, Homogeneous Pd Catalysts,Palladium CatalystsGeneral descriptionBis(dibenzylideneacetone)palladium(0) (Pd(dba)2) is an air stable Pd0 complex. It is a reagent for the synthesis of allylic substituted cyclopentadienes. It is a homogeneous catalyst. It catalyzes the alkylation of allyl acetates by various nucleophiles under mild conditionsApplicationBis(dibenzylideneacetone)palladium(0) (Pd(dba)2) was employed as catalyst in the following studies:-Synthesis of isomeric 2-aryl-2,5-dihydrofurans, via Heck coupling of aryl bromides with alkenes using neopentyl phosphine ligands.-Heck reaction of benzyl trifluoroacetate and 2,3-dihydrofuran phosphoramidite ligand.-Allylation of stabilized anions.-Cross coupling of allyl, alkenyl and aryl halides with organostannanes.-Cross coupling of vinyl halides with alkenyl zinc species.-Carbonylation of alkenyl and aryl halides.-Employed with cyclic thiourea ligands in an efficient aerobic oxidation of alcohols to aldehydes and ketones.
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Tris(dibenzylideneacetone)dipalladium(0)Tris(dibenzylideneacetone)dipalladiumpd2(dba)3Buy pd2(dba)3 Buy C51H42O3Pd2 Buy CAS 51364-51-3Buy Tris(dibenzylideneacetone)dipalladium(0) JDchem CAS No. 51364-51-3 Molecular Formula:C51H42O3Pd2Molecular Weight:915.7 g/molpurity: 98%,Pd>21.5%Apperance:Black purple powder storage: Sealed, dry, protected from light shelf life: 24 monthMelting point:152-155℃Water solubility:insolublesupplier: JDchemKeywords: dipalladium , dibenzylideneacetoneISO 9001 MANUFATURERPharmaceutical compounds OLED intermediates palladium catalystApplication Palladium Catalyzed Cross-Coupling ReactionsReactant involved in:1.Synthesis of nanosized palladium phosphides upon interaction with white phosphorous2.Preparation of palladium triphenylphosphine carbonyl cluster complexes3.Precursor for synthesis of functionalized multiwalled carbon nanotube-palladium complexes used as catalysts for Heck coupling reactions4.Selective carbon-sulfur bond formation via addition of S-S and S-H bonds to alkynesCatalyst for:1. Suzuki cross-coupling reactions2. PCN- and PCS-pincer palladium complex catalyzed tandem allylationGeneral descriptionTris(dibenzylideneacetone)dipalladium(0) (Pd2(dba)3) participates in the synthesis of azepane.Crystal structure of Pd2(dba)3 has been determined by three-dimensional X-ray data. Crystals of Pd2(dba)3 are reported to crystalize in triclinic system.It is widely used Pd(0) source in Pd-mediated transformations.Its worked related to trace metals basis , Asymmetric synthesis, Catalysis or catalyst, Coupling reactions, Cross couplings, Heck Reaction, Ligands,Organic synthesis,Suzuki coupling, Polymer science, Materials Chemistry ,Column chromatography and Organic Compounds , and Arylations, Aminations, Deprotonations, Hydroxylations, Fluorinations
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中文名:乙酰丙酮钼外文名:Molybdenyl (VI) oxide bis(24pentanedionate)Bis(24pentanedionato)molybdenum(VI) DioxideAcetylacetone Molybdenum(VI)dioxy SaltBis(acetylacetonato)dioxomolybdenum(VI)Molybdenum(VI)dioxy AcetylacetonateCAS号:17524-05-9分子式:C10H14MoO6分子量:326.15线性分子式:[CH3COCH=C(O)CH3]2MoO2纯 度:≥99.0%
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中文名称:对甲基苯丙酮英文名称:4'-MethylpropiophenoneCAS号:5337-93-9外观：无色液体至淡黄色液体用途：对甲基苯丙酮是一种用于电羧化反应的化学试剂。
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作为催化剂，用于Suzuki、Kumada、Negishi等偶联反应中
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三(二亚苄基丙酮)二钯(0)是一种重要的零价钯催化剂，广泛应用于有机合成中偶联、加氢、羰基化等反应。与Chemicalbook不同的配体结合使用，原位形成高催化活性的零价钯活性物质，在碳-碳键、碳-杂原子键形成反应中得到广泛应用。
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英文名称： Solketal中文名称： 丙酮缩甘油MF： C6H12O3MW： 132.16CAS： 100-79-8
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英文名称： (S)-(+)-2,2-Dimethyl-1,3-dioxolane-4-methanol中文名称： (S)-(+)-甘油醇缩丙酮MF： C6H12O3MW： 132.16CAS： 22323-82-6
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英文名称： (R)-(-)-2,2-Dimethyl-1,3-dioxolane-4-methanol中文名称： (R)-(-)-甘油醇缩丙酮MF： C6H12O3MW： 132.16CAS： 14347-78-5
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